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Zinc-cyclen coordination to UTP, TTP or pyrophosphate induces pyrene excimer emission

Schmidt, F. and Stadlbauer, S. and König, Burkhard (2010) Zinc-cyclen coordination to UTP, TTP or pyrophosphate induces pyrene excimer emission. Dalton Transactions (39), pp. 7250-7261.

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Abstract

Pyrene labelled Zn2+-cyclen 1 and bis-Zn2+-bis-cyclen 2 complexes were synthesized. The reversible coordination at physiological pH of Zn2+-cyclens to phosphate anions and to imide moieties, as present in thymine and uracil nucleotides, is well known. In the presence of analytes bearing a phosphate and an imide or two phosphate groups the formation of a ternary complex consisting of two ...

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Item Type:Article
Date:2010
Institutions:Chemistry and Pharmacy > Institut für Organische Chemie > Lehrstuhl Prof. Dr. Burkhard König
Identification Number:
ValueType
10.1039/c0dt00001aDOI
20520892PubMed ID
Subjects:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Owner: Regina Hoheisel
Deposited On:24 Feb 2011 12:43
Last Modified:02 Nov 2011 09:52
Item ID:19896
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