Cs₂[Pt(CN)₄]•H₂O: Polarized emission and its correlation to the crystal structure

Holzapfel, W. and Yersin, Hartmut and Gliemann, G. and Otto, H. H. (1979) Cs₂[Pt(CN)₄]•H₂O: Polarized emission and its correlation to the crystal structure. Chemical Physics Letters 60, pp. 304-306.

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Abstract

In the hexagonal Cs₂[Pt(CN)₄]•H₂O compound the [Pt(CN)₄]²⁻ complex ions are arranged forming a helix. Under UV excitation the crystals strongly emit light of different polarization. It is possible to correlate the emission peak energies to the Pt-Pt distance of adjacent complexes in the helix and to determine the helix radius just from these data and the lattice constant c.

Item Type:Article
Institutions: Chemistry and Pharmacy > Institut für Physikalische und Theoretische Chemie > Chair of Chemistry III - Physical Chemistry (Light and Matter) > Prof. Dr. Hartmut Yersin
Subjects:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Owner:Prof. Dr. Hartmut Yersin
Deposited On:25 Feb 2011 09:33
Last Modified:25 Feb 2011 09:33
Item ID:19899
Owner Only: item control page