Daniels, W. and Yersin, Hartmut and v. Philipsborn, H. and Gliemann, G. (1979) X-ray diffraction and spectroscopic investigations of phase transitions in linear chain compounds. M₂[Pt(CN)₄]₃•21 H₂O with M = Dy, Er, Tb, Y. Solid State Communications 30, pp. 353-355.
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Phase transitions of single-crystal M₂[Pt(CN)₄]₃•21H₂O are investigated under temperature variation using X-ray diffraction, polarized emission and DSC-measurements. At a temperature T(trans) a jump was observed in lattice parameters and in optical transition energies. The transition is connected with an occurence of a latent transition enthalpy. This indicates a displacive phase transition of first order. Optical and X-ray data can be correlated.
|Institutions:||Chemistry and Pharmacy > Institut für Physikalische und Theoretische Chemie > Chair of Chemistry III - Physical Chemistry (Light and Matter) > Prof. Dr. Hartmut Yersin|
|Subjects:||500 Science > 540 Chemistry & allied sciences|
|Refereed:||Yes, this version has been refereed|
|Created at the University of Regensburg:||Yes|
|Owner:||Prof. Dr. Hartmut Yersin|
|Deposited On:||25 Feb 2011 13:15|
|Last Modified:||25 Feb 2011 13:15|