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URN to cite this document: urn:nbn:de:bvb:355-epub-203717
Liu, Meina (2012) Studies towards molecular catalysis with transition metal-Isonitrile complexes. PhD, Universität Regensburg
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Abstract (English)
The detailed studies on synthesis and application of a novel, well-defined polymeric Cu(I)-isonitrile complex has been described. Copper-isonitrile complex could efficiently promote Click, Ullmann-type corss coupling, Sonogashira coupling reactions. Another investigation comprises the palladium-isonitrile complex catalyzed Wacker oxidation.
From our study, clearly there is a bright future for molecular catalysis with transition metal isonitrile complex.
Translation of the abstract (German)
Eine detaillierte Studie zur Synthese und Anwendung eines neuen, wohldefinierten polymeren Kupfer(I)-Isonitrilkomplexes wurde beschrieben. Der Kupfer-Isonitrilkomplex konnte auf effiziente Weise „Click“ Reaktionen, Ullmann-ähnliche Kreuzkupplungen, sowie Sonogashira Kupplungsreaktionen antreiben. Eine weitere Untersuchung beschrieb die Palladium-Isonitrilkomplex katalysierte Wacker Oxidation.
Ausgehend von unseren Untersuchungen gibt es mit Sicherheit eine vielversprechende Zukunft für die Molekülkatalyse mit Übergangsmetall-Isonitrilkomplexen.
| Item Type: | Thesis of the University of Regensburg (PhD) |
|---|---|
| Referee: | Prof. Dr. Oliver Reiser |
| Date of exam: | 31 March 2011 |
| Institutions: | Chemistry and Pharmacy > Institut für Organische Chemie > Lehrstuhl Prof. Dr. Oliver Reiser |
| Interdisciplinary subject network: | Not selected |
| Keywords: | Isonitrile, ligand, molecular catalysis, transition metal, click reaction, Ullmann, Sonogashira, copper, iron, palladium |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Status: | Published |
| Refereed: | Yes, this version has been refereed |
| Created at the University of Regensburg: | Yes |
| Owner: | Universitätsbibliothek Regensburg |
| Deposited On: | 08 May 2012 11:13 |
| Last Modified: | 08 May 2012 11:13 |
| Item ID: | 20371 |
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