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Synthesis and reactivity of Lewis acid/base-stabilized phosphanylalanes and crystal structure determinations

URN to cite this document: urn:nbn:de:bvb:355-epub-205485

Bodensteiner, Michael (2012) Synthesis and reactivity of Lewis acid/base-stabilized phosphanylalanes and crystal structure determinations. PhD, Universität Regensburg

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Abstract (English)

Mechanistic studies on the isomerization of Lewis acid/base-stabilized phosphanylalanes were carried out on Al2P2-rings, and the oligomerization of (CO)5W-PH2AlH2-NMe3 was clarified in detail. Ethyldimethylamine, NMe2Et, was introduced as Lewis base and a new structural motif of phosphanylalanes was obtained. Systems without Lewis acids were shown to possess interesting reactivity and the ...


Translation of the abstract (German)

Sowohl die Mechanismen der Isomerisierung von Al2P2-Vierringen als auch die Oligomerisierung von (CO)5W-PH2AlH2-NMe3 wurden aufgeklärt. Mit Ethyldimethylamin, NMe2Et, als Lewis Base konnte ein bisher unbekanntes Strukturmotiv für Phosphanylalane dargestellt werden. Anhand von Lewis Säure-freie Systeme konnte eine interessante Reaktivität beschrieben werden und die Untersuchungen wurden auf Stiba- ...


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Item Type:Thesis of the University of Regensburg (PhD)
Date:1 March 2012
Referee:Prof. Dr. Manfred Scheer and Prof. Dr. Nikolaus Korber
Date of exam:8 April 2011
Institutions:Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer
Keywords:Aluminium, Phosphor, Lewis Säure, Lewis Base, Oligomerisierung, Mechanismusaufklärung, 13/15-Verbindungen, Kristallographie
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Deposited On:01 Mar 2012 08:19
Last Modified:13 Mar 2014 18:40
Item ID:20548
Owner Only: item control page


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