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Synthesis and reactivity of Lewis acid/base-stabilized phosphanylalanes and crystal structure determinations

URN to cite this document: urn:nbn:de:bvb:355-epub-205485

Bodensteiner, Michael (2012) Synthesis and reactivity of Lewis acid/base-stabilized phosphanylalanes and crystal structure determinations. PhD, Universität Regensburg

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Abstract (English)

Mechanistic studies on the isomerization of Lewis acid/base-stabilized phosphanylalanes were carried out on Al2P2-rings, and the oligomerization of (CO)5W-PH2AlH2-NMe3 was clarified in detail. Ethyldimethylamine, NMe2Et, was introduced as Lewis base and a new structural motif of phosphanylalanes was obtained. Systems without Lewis acids were shown to possess interesting reactivity and the ...

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Translation of the abstract (German)

Sowohl die Mechanismen der Isomerisierung von Al2P2-Vierringen als auch die Oligomerisierung von (CO)5W-PH2AlH2-NMe3 wurden aufgeklärt. Mit Ethyldimethylamin, NMe2Et, als Lewis Base konnte ein bisher unbekanntes Strukturmotiv für Phosphanylalane dargestellt werden. Anhand von Lewis Säure-freie Systeme konnte eine interessante Reaktivität beschrieben werden und die Untersuchungen wurden auf Stiba- ...

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Item Type:Thesis of the University of Regensburg (PhD)
Date:1 March 2012
Referee:Prof. Dr. Manfred Scheer and Prof. Dr. Nikolaus Korber
Date of exam:8 April 2011
Institutions:Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer
Keywords:Aluminium, Phosphor, Lewis Säure, Lewis Base, Oligomerisierung, Mechanismusaufklärung, 13/15-Verbindungen, Kristallographie
Subjects:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Owner: Universitätsbibliothek Regensburg
Deposited On:01 Mar 2012 08:19
Last Modified:13 Mar 2014 18:40
Item ID:20548
Owner Only: item control page

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