Bhuyan, Mouchumi and Katayev, E. and Stadlbauer, S. and Nonaka, H. and Ojida, A. and Hamachi, I. and König, Burkhard (2011) Rigid Luminescent Bis-Zinc(II)–Bis-Cyclen Complexes for the Detection of Phosphate Anions and Non-Covalent Protein Labeling in Aqueous Solution. European Journal of Organic Chemistry, 2807 -2817.
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A series of water-soluble bis- and tetrakis-ZnII–cyclen complexes with rigid structures was prepared to enhance the carboxylate and phosphate ion binding response in contrast to analogues with less-confined molecular structures. Boc-protected 6-chloro-1,3,5-triazine–bis-cyclen was coupled to different aryl and alkyl moieties in moderate to high yields and subsequently converted into the ...
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|Institutions:||Chemistry and Pharmacy > Institut für Organische Chemie > Lehrstuhl Prof. Dr. Burkhard König|
|Keywords:||Cross-coupling; Click chemistry; Palladium; Macrocycles; Luminescence; Molecular recognition|
|Subjects:||500 Science > 540 Chemistry & allied sciences|
|Refereed:||Yes, this version has been refereed|
|Created at the University of Regensburg:||Yes|
|Deposited On:||03 Jun 2011 10:11|
|Last Modified:||02 Nov 2011 09:45|