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Rigid Luminescent Bis-Zinc(II)–Bis-Cyclen Complexes for the Detection of Phosphate Anions and Non-Covalent Protein Labeling in Aqueous Solution

Bhuyan, Mouchumi and Katayev, E. and Stadlbauer, S. and Nonaka, H. and Ojida, A. and Hamachi, I. and König, Burkhard (2011) Rigid Luminescent Bis-Zinc(II)–Bis-Cyclen Complexes for the Detection of Phosphate Anions and Non-Covalent Protein Labeling in Aqueous Solution. European Journal of Organic Chemistry, 2807 -2817.

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Abstract

A series of water-soluble bis- and tetrakis-ZnII–cyclen complexes with rigid structures was prepared to enhance the carboxylate and phosphate ion binding response in contrast to analogues with less-confined molecular structures. Boc-protected 6-chloro-1,3,5-triazine–bis-cyclen was coupled to different aryl and alkyl moieties in moderate to high yields and subsequently converted into the ...

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Item Type:Article
Date:2011
Institutions:Chemistry and Pharmacy > Institut für Organische Chemie > Lehrstuhl Prof. Dr. Burkhard König
Identification Number:
ValueType
10.1002/ejoc.201100103DOI
Keywords:Cross-coupling; Click chemistry; Palladium; Macrocycles; Luminescence; Molecular recognition
Subjects:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Owner: Regina Hoheisel
Deposited On:03 Jun 2011 10:11
Last Modified:02 Nov 2011 09:45
Item ID:21095
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