Amslinger, S. and Lindner, Simon (2011) Limno-CP: A Natural Product-inspired 5-Aryl-3(2H)-furanone as Scaffold for a Library of alpha-Modified Enones. Synthesis (16), pp. 2671-2683.
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A library of 5-aryl-3(2H)-furanones that are modified in the α-position of the α,β-unsaturated carbonyl system was prepared via simple one- to three-step transformations from one common scaffold. The ¹³C NMR characterization of the enone system showed a strong influence of the α-substituents, especially on the shifts of the α- and β-carbon atoms. Probing the addition chemistry of nucleophiles versus our α-modified enones, a 1,2-addition-elimination was found, but no 1,4-addition.
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|Institutions:||Chemistry and Pharmacy > Institut für Organische Chemie > Arbeitskreis Dr. Sabine Amslinger|
|Subjects:||500 Science > 540 Chemistry & allied sciences|
|Refereed:||Yes, this version has been refereed|
|Created at the University of Regensburg:||Yes|
|Deposited On:||23 Nov 2011 16:02|
|Last Modified:||23 Oct 2012 06:37|