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Preparative, structural, and electrochemical investigations on peralkylated niobocene dichlorides and difluorides

Brunner, Henri and Gehart, G. and Meier, Walter and Wachter, Joachim and Riedel, Astrid and Elkrami, S. and Mugnier, Y. and Nuber, B. (1994) Preparative, structural, and electrochemical investigations on peralkylated niobocene dichlorides and difluorides. Organometallics 13 (1), pp. 134-140.

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Abstract

CP(dagger)2NbCl2 (CP(dagger) = 175-C5Me4Et) (1b) was synthesized from NbCl5 and a slight excess of Cp(dagger)Li and NaBH4. Its electrochemical (2 e-, E1/2 = -1.6 V) and chemical reduction (2 equiv of Na/Hg) was studied showing that peralkylation of the Cp ligand facilitates two-electron reduction compared to less substituted CP2NbHal2 derivatives. The reduced solutions of CP*2NbCl2 (CP* = C5Me5) ...

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Item Type:Article
Date:1994
Institutions:Chemistry and Pharmacy > Institut für Anorganische Chemie > Arbeitskreis Dr. Joachim Wachter
Identification Number:
ValueType
10.1021/om00013a023DOI
Subjects:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Unknown
Created at the University of Regensburg:Unknown
Owner: Universitätsbibliothek Regensburg
Deposited On:03 Jan 2012 08:34
Last Modified:13 Mar 2014 18:19
Item ID:23017
Owner Only: item control page

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