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The Reaction of [CP2+NB2(B2H6)2] (CP+ = ETA-ETME4C5) with Sulfur: Stabilization of the Tetrathioborato Ligand in Novel Sulfido Niobium Clusters

Brunner, Henri and Gehart, G. and Nuber, B. and Wachter, Joachim and Ziegler, M. L. (1992) The Reaction of [CP2+NB2(B2H6)2] (CP+ = ETA-ETME4C5) with Sulfur: Stabilization of the Tetrathioborato Ligand in Novel Sulfido Niobium Clusters. Angewandte Chemie, International Edition in English 31 (8), pp. 1021-1023.

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Abstract

An equilateral Nb3 triangle the edges of which are spanned by a BS4 tetrahedron and bridged by sulfido ligands on the ``underside'' is found in cluster 1. The synthesis of this cluster with an unusual electron configuration shows that tetrathioborates can serve as ligands in organometallic chemistry. Cp+ = ...

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Item Type:Article
Date:1992
Institutions:Chemistry and Pharmacy > Institut für Anorganische Chemie > Arbeitskreis Dr. Joachim Wachter
Identification Number:
ValueType
10.1002/anie.199210211DOI
Subjects:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Unknown
Created at the University of Regensburg:Unknown
Owner: Universitätsbibliothek Regensburg
Deposited On:04 Jan 2012 15:23
Last Modified:13 Mar 2014 18:20
Item ID:23042
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