Startseite UB

Untersuchungen zum Einfluß des Biscyclopentadienylmethanliganden auf die Bildung von Cyclopentadienylchromsulfiden ( = EFFECT OF BISCYCLOPENTADIENYLMETHANE LIGANDS ON CYCLOPENTADIENYLCHROMIUM SULFIDE FORMATION)

Brunner, Henri and Grassl, R. and Wachter, Joachim (1992) Untersuchungen zum Einfluß des Biscyclopentadienylmethanliganden auf die Bildung von Cyclopentadienylchromsulfiden ( = EFFECT OF BISCYCLOPENTADIENYLMETHANE LIGANDS ON CYCLOPENTADIENYLCHROMIUM SULFIDE FORMATION). Journal of Organometallic Chemistry 431 (2), pp. 151-157.

[img]
Preview
PDF
Download (400kB)

at publisher (via DOI)


Abstract

The reaction of bcpmCr2(CO)6 (bcpm = biscyclopentadienylmethane) with sulfur gives in a stepwise reaction the complexes bcpmCr2(CO)4S (2) and bcpm2Cr4S4 (3). The products were investigated by IR and low temperature H-1 NMR spectroscopy. The H-1 NMR spectra of 2 show upon cooling a dynamic process similar to that in the starting material. It is ascribed to a topomerization process in the bridging ...

plus


Export bibliographical data

Item Type:Article
Date:1992
Institutions:Chemistry and Pharmacy > Institut für Anorganische Chemie > Arbeitskreis Dr. Joachim Wachter
Identification Number:
ValueType
10.1016/0022-328X(92)80114-DDOI
Subjects:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Unknown
Created at the University of Regensburg:Unknown
Owner: Universitätsbibliothek Regensburg
Deposited On:04 Jan 2012 15:25
Last Modified:13 Mar 2014 18:20
Item ID:23044
Owner Only: item control page
  1. University

University Library

Publication Server

Contact person
Gernot Deinzer

Telefon 0941 943-2759
Contact