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Synthese und strukturelle Charakterisierung von Bis(pentamethylcyclopentadienylmolybdän-μ-sulfido)-Komplexen mit μ,η1-SSR-Liganden(= SYNTHESIS AND STRUCTURAL CHARACTERIZATION OF BIS(PENTAMETHYLCYCLOPENTADIENYLMOLYBDENUM-MU-SULFIDO) COMPLEXES WITH MU,ETA-1-SSR LIGANDS)

Brunner, Henri and Grassl, R. and Wachter, Joachim and Nuber, B. and Ziegler, M. L. (1992) Synthese und strukturelle Charakterisierung von Bis(pentamethylcyclopentadienylmolybdän-μ-sulfido)-Komplexen mit μ,η1-SSR-Liganden(= SYNTHESIS AND STRUCTURAL CHARACTERIZATION OF BIS(PENTAMETHYLCYCLOPENTADIENYLMOLYBDENUM-MU-SULFIDO) COMPLEXES WITH MU,ETA-1-SSR LIGANDS). Journal of Organometallic Chemistry 427 (1), pp. 57-62.

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Abstract

The reaction of Cp2*Mo2S4I2(Cp* = eta(5)-C5Me5) with two equivalents of NaSR (R = Me, (i)Pr, (t)Bu, Ph) gives the complexes Cp2*Mo2(mu,eta(1)-SSR)2(mu-S)2 (2a-d) in nearly quantitative yields. The compounds have been investigated spectroscopically and in the case of R = Ph (2d) by means of X-ray diffraction analysis. The results show the presence of two eta(1)-PhSS- bridges (d(s-s) 2.139(2) ...

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Item Type:Article
Date:1992
Institutions:Chemistry and Pharmacy > Institut für Anorganische Chemie > Arbeitskreis Dr. Joachim Wachter
Identification Number:
ValueType
10.1016/0022-328X(92)83205-VDOI
Subjects:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Unknown
Created at the University of Regensburg:Unknown
Owner: Universitätsbibliothek Regensburg
Deposited On:04 Jan 2012 15:21
Last Modified:13 Mar 2014 18:20
Item ID:23045
Owner Only: item control page
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