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Neue Aspekte in der Chemie von Übergangsmetallpolysulfidkomplexen: Synthese und Kristallstrukturen von Cp′3Nb3S12 und Cp′3Nb3S10O (Cp′ = t-BuC5H4)

Brunner, Henri and Meier, W. and Wachter, Joachim and Nuber, Bernd and Ziegler, M. L. (1990) Neue Aspekte in der Chemie von Übergangsmetallpolysulfidkomplexen: Synthese und Kristallstrukturen von Cp′3Nb3S12 und Cp′3Nb3S10O (Cp′ = t-BuC5H4). Journal of Organometallic Chemistry 381 (1), C7-C12.

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Abstract

Thermolysis of a mixture of Cp′4Nb2Sn (Cp′ = t-BuC5H4; n = 8, 9) results in the formation of the new niobium polysulfide complexes: Cp′3Nb3S12 (2), Cp′3Nb3S10O (3), Cp′3Nb3S10O (4) and Cp′4Nb4S13 (5). The structures of 2 and 3 have been established by X-ray diffraction studies. The complexes are characterized by an unusual variety of different sulfur ligands (up to five in 2), which is responsible for the absence of any metal-metal interaction.


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Item Type:Article
Date:1990
Institutions:Chemistry and Pharmacy > Institut für Anorganische Chemie > Alumni or Retired Professors > Arbeitskreis Dr. Joachim Wachter
Identification Number:
ValueType
10.1016/0022-328X(90)85458-BDOI
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Unknown
Deposited On:09 Jan 2012 12:45
Last Modified:13 Mar 2014 18:21
Item ID:23052
Owner Only: item control page

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