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Improvement of (bipy)Pt(XR)₂ (X = O; S) type photosensitiezers by covalent dye attachment

Pevny, F. and Zabel, Manfred and Winter, Rainer F. and Rausch, A. F. and Yersin, Hartmut and Tuczek, F. and Zalis, S. (2011) Improvement of (bipy)Pt(XR)₂ (X = O; S) type photosensitiezers by covalent dye attachment. Chemical Communications (47), pp. 6302-6304.

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Abstract

Irradiation into the dye-based absorption band of complexes
(tBu₂bipy)Pt(SR)₂ and (tBu₂bipy)Pt(OR)₂ where R denotes a
coumarine-based thiolate and alkoxolate substituent populates
the same excited triplet state as is obtained by excitation into the
much weaker (RX)₂Pt-tBu₂bipy (X = O, S) charge-transfer band.
This paves the way toward more efficient photosensitizers.


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Item Type:Article
Date:2011
Institutions:Chemistry and Pharmacy > Institut für Physikalische und Theoretische Chemie > Chair of Chemistry III - Physical Chemistry (Molecular Spectroscopy and Photochemistry) > Prof. Dr. Hartmut Yersin
Identification Number:
ValueType
10.1039/c0cc04443aDOI
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Partially
Deposited On:02 Mar 2012 10:51
Last Modified:02 Mar 2012 10:51
Item ID:23519
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