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Complexity in "Simple" Electrolyte Solutions: Ion Pairing in MgSO4(aq)

Buchner, Richard and Chen, T. and Hefter, Glenn (2004) Complexity in "Simple" Electrolyte Solutions: Ion Pairing in MgSO4(aq). Journal of Physical Chemistry B 108 (7), pp. 2365-2375.

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A detailed investigation of aq. solns. of MgSO4 has been made by dielec. relaxation spectroscopy over a wide range of frequencies (0.2 ≤ ν/GHz ≤ 89) and concns. (0.017 ≤ c/M ≤ 2.24). Detailed anal. of the spectra shows conclusively, as has long been inferred from ultrasonic absorption studies, the simultaneous presence of double solvent sepd. (2SIP), solvent-shared (SIP), and contact (CIP) ion ...


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Item type:Article
Institutions:Chemistry and Pharmacy > Institut für Physikalische und Theoretische Chemie > Chair of Chemistry VI - Physical Chemistry (Solution Chemistry) > PD Dr. Richard Buchner
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Keywords:magnesium sulfate aq soln ion pairing dielec relaxation Raman
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Deposited on:15 May 2012 13:30
Last modified:15 May 2012 13:30
Item ID:24351
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