Lima, E.R.A. and Boström, M. and Sernelius, B.E. and Horinek, Dominik and Netz, R.R and Biscaia, E.C. and Kunz, Werner and Tavares, F.W. (2008) Forces between air-bubbles in electrolyte solution. Chemical Physics Letters 458 (4-6), pp. 299-302.
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Ion specificity plays a key role in soln. chem. and many biol. processes. However, the classical DLVO theory was not able to explain the exptl. obsd. ion specific forces acting between air-bubbles in electrolyte solns. The authors resolve this problem by using a generalized Poisson-Boltzmann equation. Inclusion of both short-range potentials obtained from simulation (acting between ions and the air-H2O interface) and the spatial variation of the local dielec. const. near the air-H2O interface may be essential to obtain correct results.
|Institutions:||Chemistry and Pharmacy > Institut für Physikalische und Theoretische Chemie > Chair of Chemistry VI - Physical Chemistry (Solution Chemistry) > Prof. Dr. Werner Kunz|
|Keywords:||bubble force electrolyte soln|
|Subjects:||500 Science > 540 Chemistry & allied sciences|
|Refereed:||Yes, this version has been refereed|
|Created at the University of Regensburg:||Yes|
|Deposited On:||21 May 2012 13:04|
|Last Modified:||21 May 2012 13:04|