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Co-Ion and Ion Competition Effects: Ion Distributions Close to a Hydrophobic Solid Surface in Mixed Electrolyte Solutions

Lima, E.R.A. and Boström, M. and Horinek, Dominik and Netz, R.R and Biscaia, E.C. and Kunz, Werner and Tavares, F.W. (2008) Co-Ion and Ion Competition Effects: Ion Distributions Close to a Hydrophobic Solid Surface in Mixed Electrolyte Solutions. Langmuir 24 (8), pp. 3944-3948.

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Abstract

We consider within a modified Poisson-Boltzmann theory an electrolyte, with different mixts. of NaCl and NaI, near uncharged and charged solid hydrophobic surfaces. The parametrized potentials of mean force acting on Na+, Cl-, and I- near an uncharged self-assembled monolayer were deduced from mol. simulations with polarizable force fields. We study what happens when the surface presents neg. ...

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Item Type:Article
Date:2008
Institutions:Chemistry and Pharmacy > Institut für Physikalische und Theoretische Chemie > Chair of Chemistry VI - Physical Chemistry (Solution Chemistry) > Prof. Dr. Werner Kunz
Identification Number:
ValueType
10.1021/la7037069DOI
Keywords:ion distribution hydrophobic solid surface mixed electrolyte soln
Subjects:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Owner: Georg Berger
Deposited On:22 May 2012 09:23
Last Modified:22 May 2012 09:23
Item ID:24466
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