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Is There an Anionic Hofmeister Effect on Water Dynamics? Dielectric Spectroscopy of Aqueous Solutions of NaBr, NaI, NaNO3, NaClO4, and NaSC

Wachter, Wolfgang and Kunz, Werner and Buchner, Richard and Hefter, Glenn (2005) Is There an Anionic Hofmeister Effect on Water Dynamics? Dielectric Spectroscopy of Aqueous Solutions of NaBr, NaI, NaNO3, NaClO4, and NaSC. Journal of Physical Chemistry A 109 (39), pp. 8675-8683.

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Abstract

A systematic study of the dielec. relaxation spectra of aq. solns. of NaBr, NaI, NaNO3, NaClO4, and NaSCN was made over a wide range of frequencies (0.2 ≤ ν/GHz ≤ 89) and solute concns. (0.05 ≤ c/M ≤ 1.5) at 25°. The spectra could be adequately described by a single Cole-Cole (CC) process, sym. broadened relative to that of pure water. However, similar quality fits were also obtained with a ...

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Item Type:Article
Date:2005
Institutions:Chemistry and Pharmacy > Institut für Physikalische und Theoretische Chemie > Chair of Chemistry VI - Physical Chemistry (Solution Chemistry) > Prof. Dr. Werner Kunz
Identification Number:
ValueType
10.1021/jp053299mDOI
Keywords:dielec relaxation alk metal salt aq soln Hofmeister effect
Subjects:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Owner: Georg Berger
Deposited On:24 May 2012 08:30
Last Modified:24 May 2012 08:30
Item ID:24542
Owner Only: item control page
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