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Osmotic coefficients and surface tensions of aqueous electrolyte solutions: Role of dispersion forces

Kunz, Werner and Belloni, L. and Bernard, Olivier and Ninham, Barry W. (2004) Osmotic coefficients and surface tensions of aqueous electrolyte solutions: Role of dispersion forces. Journal of Physical Chemistry B 108 (7), pp. 2398-2404.

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Abstract

Osmotic coeffs. of a series of 16 aq. electrolyte solns. are described at concns. ≤1 M with the help of HNC calcns. and solvent-averaged potentials of charged hard spheres with an addnl. necessary dispersion potential, omitted from all earlier treatments. The adjusted ionic radii and excess polarizabilities have values of the expected order of magnitude. Whereas the description of the bulk ...

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Item Type:Article
Date:2004
Institutions:Chemistry and Pharmacy > Institut für Physikalische und Theoretische Chemie > Chair of Chemistry VI - Physical Chemistry (Solution Chemistry) > Prof. Dr. Werner Kunz
Identification Number:
ValueType
10.1021/jp036113xDOI
Keywords:electrolytic soln osmotic coeff surface tension calcn dispersion force
Subjects:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Owner: Georg Berger
Deposited On:29 May 2012 08:35
Last Modified:29 May 2012 08:35
Item ID:24599
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