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Complex Formation in Aqueous Trimethylamine-N-oxide (TMAO) Solutions

Hunger, J. and Tielrooij, K.-J. and Buchner, Richard and Bonn, M. and Bakker, H. (2012) Complex Formation in Aqueous Trimethylamine-N-oxide (TMAO) Solutions. Journal of Physical Chemistry B 116 (16), pp. 4783-4795.

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We study aq. solns. of the amphiphilic osmolyte trimethylamine-N-oxide (TMAO) using broadband dielec. spectroscopy and femtosecond mid-IR spectroscopy. Both expts. provide strong evidence for distinctively slower rotation dynamics for water mols. interacting with the hydrophobic part of the TMAO mols. Further, water is found to interact more strongly at the hydrophilic site of the TMAO mols.: ...


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Item Type:Article
Institutions:Chemistry and Pharmacy > Institut für Physikalische und Theoretische Chemie > Chair of Chemistry VI - Physical Chemistry (Solution Chemistry) > PD Dr. Richard Buchner
Identification Number:
Keywords:complex formation aq soln trimethylamine oxide
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Deposited On:05 Jun 2012 11:49
Last Modified:05 Jun 2012 11:49
Item ID:24698
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