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Association of ionic liquids in solution: a combined dielectric and conductivity study of [bmim][Cl] in water and in acetonitrile

Bester-Rogac, M. and Stoppa, A. and Hunger, J. and Hefter, Glenn and Buchner, Richard (2011) Association of ionic liquids in solution: a combined dielectric and conductivity study of [bmim][Cl] in water and in acetonitrile. Physical Chemistry Chemical Physics 13 (39), pp. 17588-17598.

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Abstract

The ion assocn. in solns. of 1-N-butyl-3-N-methylimidazolium chloride ([bmim][Cl]) in acetonitrile and in water was studied by dielec. spectroscopy for salt concns. c ≤ 1.3 M at 298.15 K and by measurement of molar elec. conductivities, Λ, of dil. solns. (c ≤ 0.006 M) in the temp. range 273.15 .ltorsim. T/K ≤ 313.15. While acetonitrile solns. of [bmim][Cl] exhibit moderate ion pairing, with an ...

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Item Type:Article
Date:2011
Institutions:Chemistry and Pharmacy > Institut für Physikalische und Theoretische Chemie > Chair of Chemistry VI - Physical Chemistry (Solution Chemistry) > PD Dr. Richard Buchner
Identification Number:
ValueType
10.1039/c1cp21371gDOI
Keywords:ion pair soln butylmethyimidazolium chloride acetonitrile water dielec spectroscopy elec cond ion pair soln butylmethyimidazolium chloride acetonitrile water
Subjects:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Owner: Georg Berger
Deposited On:05 Jun 2012 11:41
Last Modified:02 Jul 2012 14:18
Item ID:24703
Owner Only: item control page
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