Deutsch
Dadova, Jitka and Svobodova, Eva and Sikorski, Marek and König, Burkhard and Cibulka, Radek (2012) Photooxidation of Sulfides to Sulfoxides Mediated by Tetra-O-Acetylriboflavin and Visible Light. ChemCatChem 4 (5), pp. 620-623.
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Abstract
Chemoselective photooxidation: Tetra-O-acetylriboflavin and blue light mediate the selective oxidation of sulfides to sulfoxides without overoxidation to sulfones. Reaction is very effective in ethanol/water (95:5,v/v) mixture reaching a quantum yield of Φ=0.60. The photooxidation reaction scope includes aliphatic and aromatic sulfides including sterically hindered substrates.
| Item Type: | Article | ||||
|---|---|---|---|---|---|
| Institutions: | Chemistry and Pharmacy > Institut für Organische Chemie > Lehrstuhl Prof. Dr. Burkhard König | ||||
| Projects: | GRK 1626 Chemische Photokatalyse | ||||
| Identification Number: |
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| Keywords: | flavins · photooxidation · singlet oxygen · sulfides · sulfoxidation | ||||
| Subjects: | 500 Science > 540 Chemistry & allied sciences | ||||
| Status: | Published | ||||
| Refereed: | Yes, this version has been refereed | ||||
| Created at the University of Regensburg: | Yes | ||||
| Owner: | Regina Hoheisel | ||||
| Deposited On: | 06 Jun 2012 13:23 | ||||
| Last Modified: | 28 Sep 2012 11:48 | ||||
| Item ID: | 24706 |
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