Deutsch
Vacha, Robert and Horinek, Dominik and Buchner, Richard and Winter, B. and Jungwirth, Pavel (2010) An explanation for the charge on water's surface, by A. Gray-Weale and J. K. Beattie, Phys. Chem. Chem. Phys., 2009, 11, 10994. Comment. Physical Chemistry Chemical Physics 12 (14), pp. 14362-14363.
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Abstract
Gray-Weale and Beattie's rationalization of the neg. charge obsd. on the surface of water in terms of accumulation of OH- is based on the supposedly uniquely large dielec. decrement of hydroxide solns. [A. Gray-Weale and J. K. Beattie, Phys. Chem. Chem. Phys., 2009, 11, 10994]. We challenge this rationalization and point to another ion, namely fluoride, which has a comparable dielec. decrement and size and which is repelled from the surface of water.
| Item Type: | Article | ||||
|---|---|---|---|---|---|
| Institutions: | Chemistry and Pharmacy > Institut für Physikalische und Theoretische Chemie > Chair of Chemistry VI - Physical Chemistry (Solution Chemistry) > PD Dr. Richard Buchner | ||||
| Identification Number: |
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| Subjects: | 500 Science > 540 Chemistry & allied sciences | ||||
| Status: | Published | ||||
| Refereed: | Yes, this version has been refereed | ||||
| Created at the University of Regensburg: | Yes | ||||
| Owner: | Georg Berger | ||||
| Deposited On: | 08 Jun 2012 12:58 | ||||
| Last Modified: | 08 Jun 2012 12:58 | ||||
| Item ID: | 24734 |
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