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An explanation for the charge on water's surface, by A. Gray-Weale and J. K. Beattie, Phys. Chem. Chem. Phys., 2009, 11, 10994. Comment

Vacha, Robert and Horinek, Dominik and Buchner, Richard and Winter, B. and Jungwirth, Pavel (2010) An explanation for the charge on water's surface, by A. Gray-Weale and J. K. Beattie, Phys. Chem. Chem. Phys., 2009, 11, 10994. Comment. Physical Chemistry Chemical Physics 12 (14), pp. 14362-14363.

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Abstract

Gray-Weale and Beattie's rationalization of the neg. charge obsd. on the surface of water in terms of accumulation of OH- is based on the supposedly uniquely large dielec. decrement of hydroxide solns. [A. Gray-Weale and J. K. Beattie, Phys. Chem. Chem. Phys., 2009, 11, 10994]. We challenge this rationalization and point to another ion, namely fluoride, which has a comparable dielec. decrement ...

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Item Type:Article
Date:2010
Institutions:Chemistry and Pharmacy > Institut für Physikalische und Theoretische Chemie > Chair of Chemistry VI - Physical Chemistry (Solution Chemistry) > PD Dr. Richard Buchner
Identification Number:
ValueType
10.1039/c001492cDOI
Subjects:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Owner: Georg Berger
Deposited On:08 Jun 2012 10:58
Last Modified:08 Jun 2012 10:58
Item ID:24734
Owner Only: item control page
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