Buchner, Richard and Hefter, Glenn (2009) Interactions and dynamics in electrolyte solutions by dielectric spectroscopy. Physical Chemistry Chemical Physics 11 (40), pp. 8984-8999.
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A review. Despite its immense abilities to quantify many aspects of ion-ion and ion-solvent interactions, dielec. relaxation spectroscopy (DRS) has long been neglected as a tool for the investigation of the structure and dynamics of electrolyte solns. The reasons for this are briefly discussed and it is shown that many of the difficulties assocd. with this technique have been overcome in recent years by technol. developments. Representative applications of DRS to the investigation of ion solvation and ion assocn. in electrolyte solns. of chem., industrial, geochem. and biol. interest, including room temp. ionic liqs. and polyelectrolyte systems, are discussed. The advantages of linking DRS measurements to information obtained from other exptl. techniques and from computer simulations are highlighted.
|Institutions:||Chemistry and Pharmacy > Institut für Physikalische und Theoretische Chemie > Chair of Chemistry VI - Physical Chemistry (Solution Chemistry) > PD Dr. Richard Buchner|
|Keywords:||review dielec relaxation spectroscopy ion interaction dynamics electrolyte soln|
|Subjects:||500 Science > 540 Chemistry & allied sciences|
|Refereed:||Yes, this version has been refereed|
|Created at the University of Regensburg:||Yes|
|Deposited On:||06 Jun 2012 13:38|
|Last Modified:||06 Jun 2012 13:38|