Stoppa, A. and Hunger, J. and Buchner, Richard (2009) Conductivities of Binary Mixtures of Ionic Liquids with Polar Solvents. Journal of Chemical & Engineering Data 54 (2), pp. 472-479.
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Data for the cond., κ, of selected binary mixts. of the ionic liqs. [emim][BF4], [bmim][BF4], [bmim][PF6], [bmim][DCA], and [hmim][BF4] with polar solvents (water, propylene carbonate, DMSO, methanol, dichloromethane) at 25 °C are reported. Addnl., mixt. densities, ρ, were detd. to convert κ into molar cond., Λ. The obtained results were fitted by appropriate interpolation formulas. Where possible, data were compared with information from the literature. Electrode polarization and sample purity, including [BF-4] hydrolysis, were considered as possible sources of errors in κ. The effect of viscosity on the accuracy of ρ and thus Λ was checked and considered as negligible.
|Institutions:||Chemistry and Pharmacy > Institut für Physikalische und Theoretische Chemie > Chair of Chemistry VI - Physical Chemistry (Solution Chemistry) > PD Dr. Richard Buchner|
|Keywords:||alkylmethylimidazolium ionic liq polar solvent binary mixt elec cond|
|Subjects:||500 Science > 540 Chemistry & allied sciences|
|Refereed:||Yes, this version has been refereed|
|Created at the University of Regensburg:||Yes|
|Deposited On:||06 Jun 2012 13:25|
|Last Modified:||06 Jun 2012 13:25|