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Intramolecular Charge Transfer Reaction, Polarity, and Dielectric Relaxation in AOT/Water/Heptane Reverse Micelles: Pool Size Dependence

Biswas, Ranjit and Rohman, Nashiour and Pradhan, Tuhin and Buchner, Richard (2008) Intramolecular Charge Transfer Reaction, Polarity, and Dielectric Relaxation in AOT/Water/Heptane Reverse Micelles: Pool Size Dependence. Journal of Physical Chemistry B 112 (31), pp. 9379-9388.

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Abstract

Intramol. charge transfer (ICT) reaction in a newly synthesized mol., of 4-(41-morpholinyl) benzonitrile (M6C), in AOT/water/heptane reverse micelles at different pool sizes has been studied by using steady-state and time-resolved fluorescence emission spectroscopy. The pool size dependences of the reaction equil. const. and reaction rate have been explained in terms of the av. polarity of the ...

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Item Type:Article
Date:2008
Institutions:Chemistry and Pharmacy > Institut für Physikalische und Theoretische Chemie > Chair of Chemistry VI - Physical Chemistry (Solution Chemistry) > PD Dr. Richard Buchner
Identification Number:
ValueType
10.1021/jp8023149DOI
Keywords:intramol charge transfer reverse micelle polarity dielec relaxation
Subjects:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Owner: Georg Berger
Deposited On:08 Jun 2012 10:39
Last Modified:08 Jun 2012 10:39
Item ID:24770
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