Buchner, Richard (2008) What can be learnt from dielectric relaxation spectroscopy about ion solvation and association? Pure and Applied Chemistry 80 (6), pp. 1239-1252.
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A review. Ion solvation and ion assocn. are key features of ion-solvent interactions, and their balance largely dets. structure, thermodn., and dynamics of electrolyte solns. Despite being studied for many years with various techniques, these effects are still intriguing because too often results obtained with different methods (each having its individual merits and limitations) cannot be connected properly due to lacking information. This review brings dielec. relaxation spectroscopy (DRS) as a further tool for soln. studies to the attention of the audience. The principles of DRS and the required instrumentation are briefly introduced. The major focus is on the kind of results obtained with this technique regarding ion solvation and assocn. and how this information compares with results obtained from other techniques.
|Institutions:||Chemistry and Pharmacy > Institut für Physikalische und Theoretische Chemie > Chair of Chemistry VI - Physical Chemistry (Solution Chemistry) > PD Dr. Richard Buchner|
|Keywords:||review ion solvation assocn dielec relaxation spectroscopy|
|Subjects:||500 Science > 540 Chemistry & allied sciences|
|Refereed:||Yes, this version has been refereed|
|Created at the University of Regensburg:||Yes|
|Deposited On:||08 Jun 2012 10:38|
|Last Modified:||08 Jun 2012 10:38|