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Interactions and Dynamics in Ionic Liquids

Stoppa, A. and Hunger, J. and Buchner, Richard and Hefter, Glenn and Thoman, A. and Helm, H. (2008) Interactions and Dynamics in Ionic Liquids. Journal of Physical Chemistry B 112 (16), pp. 4854-4858.

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Precise dielec. spectra were detd. at 25° over the exceptionally broad frequency range of 0.1 ≤ ν/GHz ≤ 3000 for the imidazolium-based room-temp. ionic liqs. (RTILs) [bmim][BF4], [bmim][PF6], [bmim][DCA], and [hmim][BF4]. The spectra are dominated by a low-frequency process at ∼1 GHz with a broad relaxation time distribution of the Cole-Davidson or Cole-Cole type, which is thought to correspond ...


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Item type:Article
Institutions:Chemistry and Pharmacy > Institut für Physikalische und Theoretische Chemie > Chair of Chemistry VI - Physical Chemistry (Solution Chemistry) > PD Dr. Richard Buchner
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Keywords:solute ionic liq intermol dynamics interaction solvation
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Deposited on:08 Jun 2012 10:36
Last modified:08 Jun 2012 10:36
Item ID:24773
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