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Ion association and hydration in 3:2 electrolyte solutions by dielectric spectroscopy: aluminum sulfate

Schrödle, S. and Rudolph, W.W. and Hefter, Glenn and Buchner, Richard (2007) Ion association and hydration in 3:2 electrolyte solutions by dielectric spectroscopy: aluminum sulfate. Geochimica et Cosmochimica Acta 71 (22), pp. 5287-5300.

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Abstract

Broadband dielec. measurements utilizing state-of-the-art coaxial reflectometry and traveling-wave interferometry have been made on aq. solns. of the 3:2 electrolyte aluminum sulfate at 25° over the frequency range 0.2 ≤ ν (GHz) ≤ 89 and at total solute concns. 0.012 ≤ c (M) ≤ 0.65. Detailed anal. of the solute contribution to the dielec. spectra revealed the simultaneous presence of double ...

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Item Type:Article
Date:2007
Institutions:Chemistry and Pharmacy > Institut für Physikalische und Theoretische Chemie > Chair of Chemistry VI - Physical Chemistry (Solution Chemistry) > PD Dr. Richard Buchner
Identification Number:
ValueType
10.1016/j.gca.2007.08.026DOI
Keywords:aluminum sulfate aq soln ion pairing hydration dielec relaxation
Subjects:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Owner: Georg Berger
Deposited On:11 Jun 2012 05:41
Last Modified:11 Jun 2012 05:41
Item ID:24777
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