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Ion association and hydration in aqueous solutions of LiCl and Li2SO4 by dielectric spectroscopy

Wachter, Wolfgang and Fernandez, Sarka and Buchner, Richard and Hefter, Glenn (2007) Ion association and hydration in aqueous solutions of LiCl and Li2SO4 by dielectric spectroscopy. Journal of Physical Chemistry B 111 (30), pp. 9010-9017.

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Abstract

A systematic study of the dielec. relaxation spectra of aq. solns. of LiCl and Li2SO4 has been made at solute concns. of 0.05 ≤ c/M ≤ 1.0 and 2.0, resp., and over a wide range of frequencies (0.2 ≤ ν/GHz ≤ 89) at 25°. The spectra were best described by a superposition of four Debye processes, consisting of the two well-known water relaxations at ca. 8 and 0.5 ps and two ion-pair contributions at ...

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Item Type:Article
Date:2007
Institutions:Chemistry and Pharmacy > Institut für Physikalische und Theoretische Chemie > Chair of Chemistry VI - Physical Chemistry (Solution Chemistry) > PD Dr. Richard Buchner
Identification Number:
ValueType
10.1021/jp072425eDOI
Keywords:lithium chloride sulfate aq soln ion pairing hydration
Subjects:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Owner: Georg Berger
Deposited On:11 Jun 2012 05:40
Last Modified:11 Jun 2012 05:40
Item ID:24778
Owner Only: item control page
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