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Dielectric Spectroscopy of Hydrogen Bond Dynamics and Microheterogenity of Water + Dioxane Mixtures

Schrödle, S. and Hefter, Glenn and Buchner, Richard (2007) Dielectric Spectroscopy of Hydrogen Bond Dynamics and Microheterogenity of Water + Dioxane Mixtures. Journal of Physical Chemistry B 111 (21), pp. 5946-5951.

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Abstract

Mixts. of water or D2O + 1,4-dioxane (DX) have been studied at 25 °C by dielec. relaxation spectroscopy over a wide range of frequencies (0.2 ≤ ν/GHz ≤ 89) for DX mole fractions 0 ≤ x2 ≤ 0.67. The spectra were best fitted by the sum of two Debye terms. The slower process was assigned to the cooperative relaxation of the hydrogen-bond network of water, whereas the faster mode reflects the ...

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Item Type:Article
Date:2007
Institutions:Chemistry and Pharmacy > Institut für Physikalische und Theoretische Chemie > Chair of Chemistry VI - Physical Chemistry (Solution Chemistry) > PD Dr. Richard Buchner
Identification Number:
ValueType
10.1021/jp0713413DOI
Keywords:dielec spectroscopy hydrogen bond dynamics microheterogeneity water dioxane mixt
Subjects:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Owner: Georg Berger
Deposited On:11 Jun 2012 05:39
Last Modified:11 Jun 2012 05:39
Item ID:24779
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