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Picosecond dynamics and microheterogenity of water+dioxane mixtures

Schrödle, S. and Fischer, Bernd and Helm, H. and Buchner, Richard (2007) Picosecond dynamics and microheterogenity of water+dioxane mixtures. The journal of Physical Chemistry. A 111 (11), pp. 2043-2046.

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Dielectric spectra from 200 MHz up to 3 THz were determined to study the fast dynamics of dilute water+1,4-dioxane. epsilon(nu) could be fitted by a collision induced oscillator at high frequencies plus two Debye relaxations in the microwave region. Isotope substitution was used to assign water and dioxane modes. The presence of the cooperative hydrogen-bond network relaxation down to a water ...


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Item type:Article
Institutions:Chemistry and Pharmacy > Institut für Physikalische und Theoretische Chemie > Chair of Chemistry VI - Physical Chemistry (Solution Chemistry) > PD Dr. Richard Buchner
Identification Number:
17388290PubMed ID
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Deposited on:11 Jun 2012 05:38
Last modified:03 Jul 2012 08:40
Item ID:24780
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