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Temperature effects on ion association and hydration in MgSO4 by dielectric spectroscopy

Akilan, C. and Rohman, Nashiour and Hefter, Glenn and Buchner, Richard (2006) Temperature effects on ion association and hydration in MgSO4 by dielectric spectroscopy. ChemPhysChem 7 (11), pp. 2319-2330.

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Abstract

A detailed investigation of aq. solns. of magnesium sulfate has been made by dielec. relaxation spectroscopy (DRS) over a wide range of frequencies (0.2 ≤ ν/GHz ≤ 89), concns. (0.02 ≤ m/mol kg-1 ≤ 2.3) and temps. (5 ≤ .vtheta./°C ≤ 65). Consistent with literature data from other techniques, the spectra show clear evidence at all temps. for the simultaneous existence of double solvent-sepd. ...

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Item Type:Article
Date:2006
Institutions:Chemistry and Pharmacy > Institut für Physikalische und Theoretische Chemie > Chair of Chemistry VI - Physical Chemistry (Solution Chemistry) > PD Dr. Richard Buchner
Identification Number:
ValueType
10.1002/cphc.200600342DOI
Keywords:magnesium sulfate hydration ion pairing temp effect dielec spectroscopy
Subjects:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Owner: Georg Berger
Deposited On:11 Jun 2012 05:34
Last Modified:11 Jun 2012 05:34
Item ID:24783
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