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Ion Association and Hydration in Aqueous Solutions of Copper(II) Sulfate from 5 to 65 °C by Dielectric Spectroscopy

Akilan, C. and Hefter, Glenn and Rohman, Nashiour and Buchner, Richard (2006) Ion Association and Hydration in Aqueous Solutions of Copper(II) Sulfate from 5 to 65 °C by Dielectric Spectroscopy. Journal of Physical Chemistry B 110 (30), pp. 14961-14970.

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Abstract

Aq. solns. of copper(II) sulfate have been studied by dielec. relaxation spectroscopy (DRS) over a wide range of frequencies (0.2 .ltorsim. ν/GHz ≤ 89), concns. (0.02 ≤ m/mol kg-1 .ltorsim. 1.4), and temps. (5 ≤ t/°C ≤ 65). The spectra show clear evidence for the simultaneous existence of double-solvent-sepd., solvent-shared, and contact ion pairs at all temps., with increasing formation esp. of ...

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Item Type:Article
Date:2006
Institutions:Chemistry and Pharmacy > Institut für Physikalische und Theoretische Chemie > Chair of Chemistry VI - Physical Chemistry (Solution Chemistry) > PD Dr. Richard Buchner
Identification Number:
ValueType
10.1021/jp0620769DOI
Keywords:copper sulfate aq soln hydration ion pairing dielec spectroscopy thermodn ion pairing copper sulfate aq soln dielec spectroscopy
Subjects:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Owner: Georg Berger
Deposited On:11 Jun 2012 05:31
Last Modified:11 Jun 2012 05:31
Item ID:24785
Owner Only: item control page
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