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Hydration of Tetraphenylphosphonium and Tetraphenylborate Ions by Dielectric Relaxation Spectroscopy

Wachter, Wolfgang and Buchner, Richard and Hefter, Glenn (2006) Hydration of Tetraphenylphosphonium and Tetraphenylborate Ions by Dielectric Relaxation Spectroscopy. Journal of Physical Chemistry B 110 (10), pp. 5147-5154.

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Abstract

A systematic study of the dielec. relaxation spectra of aq. solns. of NaBPh4 and Ph4PCl has been made at solute concns. of 0.02 ≤ c/M ≤ 0.82 and 0.20, resp., and over a wide range of frequencies (0.2 ≤ ν/GHz ≤ 89) at 25 °C. The spectra were best described by a superposition of four Debye processes, consisting of a very small ion-pair contribution with an av. relaxation time of about 300 ps, a ...

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Item Type:Article
Date:2006
Institutions:Chemistry and Pharmacy > Institut für Physikalische und Theoretische Chemie > Chair of Chemistry VI - Physical Chemistry (Solution Chemistry) > PD Dr. Richard Buchner
Identification Number:
ValueType
10.1021/jp057189rDOI
Keywords:phenylphosphonium phenylborate selective hydration dielec relaxation spectroscopy
Subjects:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Owner: Georg Berger
Deposited On:11 Jun 2012 08:55
Last Modified:11 Jun 2012 08:55
Item ID:24789
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