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Ion association and solvation of perchlorate salts in N,N-dimethylformamide and N,N-dimethylacetamide

Wurm, B. and Münsterer, M. and Richardi, J. and Buchner, Richard and Barthel, Josef (2005) Ion association and solvation of perchlorate salts in N,N-dimethylformamide and N,N-dimethylacetamide. Journal of Molecular Liquids 119 (1-3), pp. 97-106.

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The results of dielec. relaxation expts. on solns. of LiClO4, NaClO4 and Bu4NClO4 in N,N-dimethylformamide (DMF), and N,N-dimethylacetamide (DMA), performed at 25 °C in the frequency range 0.2 ≤ ν/GHz ≤ 89 are presented. For all electrolytes, a solute relaxation process due to ion pairs is obsd. in addn. to the solvent relaxation. The alkali salts form predominantly solvent-shared ion pairs in ...


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Item type:Article
Institutions:Chemistry and Pharmacy > Institut für Physikalische und Theoretische Chemie > Chair of Chemistry VI - Physical Chemistry (Solution Chemistry) > PD Dr. Richard Buchner
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Keywords:lithium sodium butylammonium perchlorate amide soln solvation ion pairing
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Deposited on:11 Jun 2012 09:09
Last modified:11 Jun 2012 09:09
Item ID:24800
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