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Dielectric relaxation of aqueous electrolyte solutions. II. Ion-pair relaxation of 1:2, 2:1, and 2:2 electrolytes

Barthel, Josef and Hetzenauer, H. and Buchner, Richard (1992) Dielectric relaxation of aqueous electrolyte solutions. II. Ion-pair relaxation of 1:2, 2:1, and 2:2 electrolytes. Berichte der Bunsen-Gesellschaft 96, pp. 988-997.

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Abstract

The low-frequency relaxation process contributing to the complex permittivity spectra of aq. solns. of MgSO4, CdSO4, Na2SO4, CdCl2, and CuCl2 is investigated. The dispersion amplitudes are analyzed with the help of model calcns., based on a modified Cavell equation for ellipsoidal bodies. Ion pairs are responsible for the low-frequency relaxation process with solvent sepd. ion pairs dominating ...

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Item Type:Article
Date:1992
Institutions:Chemistry and Pharmacy > Institut für Physikalische und Theoretische Chemie > Chair of Chemistry VI - Physical Chemistry (Solution Chemistry) > PD Dr. Richard Buchner
Keywords:ion pair electrolyte soln
Subjects:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Owner: Georg Berger
Deposited On:14 Jun 2012 05:54
Last Modified:14 Jun 2012 05:55
Item ID:24878
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