Buchner, Richard and Yarwood, J. (1988) FT-far-infrared spectroscopic studies of solute-solvent interactions and molecular dynamics in solutions of methanol, N-methylformamide and N,N-dimethylformamide. Mikrochimica Acta 95 (1-6), pp. 335-337.
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Abstract
Quant. measurements of the optical consts. (4-170 cm-1) of 3 org. liqs. and their dil. solns. in CCl4 are interpreted in terms of mol. relaxation processes arising from solute-solute and solute-solvent interactions. The behavior of MeOH and HCONHMe on diln. is quite different from that of DMF, emphasizing the importance of H-bonding potentials in the former two liqs.
| Item Type: | Article | ||||
|---|---|---|---|---|---|
| Institutions: | Chemistry and Pharmacy > Institut für Physikalische und Theoretische Chemie > Chair of Chemistry VI - Physical Chemistry (Solution Chemistry) > PD Dr. Richard Buchner | ||||
| Identification Number: |
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| Keywords: | IR methanol methylformamide DMF dynamics mol dynamics methanol methylformamide DMF libration methanol methylformamide FTIR | ||||
| Subjects: | 500 Science > 540 Chemistry & allied sciences | ||||
| Status: | Published | ||||
| Refereed: | Yes, this version has been refereed | ||||
| Created at the University of Regensburg: | Yes | ||||
| Owner: | Georg Berger | ||||
| Deposited On: | 15 Jun 2012 10:47 | ||||
| Last Modified: | 15 Jun 2012 10:47 | ||||
| Item ID: | 24894 |
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