Barthel, Josef and Buchner, Richard (1986) Dielectric properties of nonaqueous electrolyte solutions. Pure and Applied Chemistry 58 (8), pp. 1077-1090.
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High-frequency permittivity of non-aq. electrolyte solns. and their solvents is reviewed in the framework of time domain and frequency domain methods. Evaluation of data is performed on the basis of models presupposing one or more relaxation processes. Depression of the solvent permittivity, relaxation times of the solvent mols., and dispersion amplitudes and relaxation times of ion-pair relaxation are investigated with regard to actual theories underlying these phenomena. Information is obtained on structural and dynamical properties of classes of electrolyte solns. based on protic H-bonding, dipolar aprotic, and low permittivity solvents and mixts. of solvents. 79 Refs.
|Institutions:||Chemistry and Pharmacy > Institut für Physikalische und Theoretische Chemie > Chair of Chemistry VI - Physical Chemistry (Solution Chemistry) > PD Dr. Richard Buchner|
|Keywords:||dielec property nonaq electrolyte soln review permittivity dielec nonaq electrolyte soln review|
|Subjects:||500 Science > 540 Chemistry & allied sciences|
|Refereed:||Yes, this version has been refereed|
|Created at the University of Regensburg:||Yes|
|Deposited On:||15 Jun 2012 08:35|
|Last Modified:||15 Jun 2012 08:35|