Seitz, Michael and Kaiser, Anja and Tereshchenko, Alexander and Geiger, Christian and Uematsu, Yukitaka and Reiser, Oliver (2006) Modular synthesis of chiral pentadentate bis(oxazoline) ligands. Tetrahedron 62 (42), pp. 9973-9980.
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Highly modular N,Y,Z,Y,N-ligands (Y=N, O, S; Z=N, NO, OH, OMe) have been prepared using bis(oxazoline) building blocks either as nucleophiles or as electrophiles in coupling reactions with central aromatic units. This way, a great variety of pentadentate bis(oxazoline) ligands in diastereo- and enantiomerically pure form become readily available, which are useful for the construction of helical metal complexes with predetermined chirality.
|Date:||16 October 2006|
|Institutions:||Chemistry and Pharmacy > Institut für Organische Chemie > Lehrstuhl Prof. Dr. Oliver Reiser|
|Subjects:||500 Science > 540 Chemistry & allied sciences|
|Refereed:||Yes, this version has been refereed|
|Created at the University of Regensburg:||Yes|
|Deposited On:||18 Oct 2007|
|Last Modified:||20 Jul 2011 21:11|