Miller, R. D. and Reiser, O. (1993) The Synthesis of Electron Donor-acceptor Substituted Pyrazoles. Journal of Heterocyclic Chemistry 30, pp. 755-763.
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A variety of 1,3- and 1,5-donor-acceptor substituted pyrazole derivatives have been synthesized by the cyclocondensation of a,b-ethynyl ketones with substituted phenyl hydrazines. The regioselectivity of the cyclization depends on the reaction conditions in a manner consistent with competitive 1,2- and 1,4-addition followed by ring closure. 1,4-Disubstituted derivatives can be prepared from the corresponding 4-iodopyrazole using palladium catalyzed carbon-carbon bond forming reactions. The pyrazole chromophores are expected to show interesting nonlinear optical properties.
|Institutions:||Chemistry and Pharmacy > Institut für Organische Chemie > Lehrstuhl Prof. Dr. Oliver Reiser|
|Subjects:||500 Science > 540 Chemistry & allied sciences|
|Refereed:||Yes, this version has been refereed|
|Created at the University of Regensburg:||Unknown|
|Owner:||Helge Knüttel (ADMIN)|
|Deposited On:||14 Aug 2006|
|Last Modified:||05 Aug 2009 13:22|