Exceptionally High Felkin-Anh Control for the Addition of Nucleophiles to a β-Amino-cyclo-propylcarbaldehyde

Bubert, Christian and Reiser, Oliver (1997) Exceptionally High Felkin-Anh Control for the Addition of Nucleophiles to a β-Amino-cyclo-propylcarbaldehyde. Tetrahedron Letters 38 (28), pp. 4985-4988.

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Other URL: http://dx.doi.org/10.1016/S0040-4039(97)01065-4

Abstract

Exceptionally high diastereocontrol in agreement with the Felkin-Anh model was observed for the addition of nucleophiles to the β-aminocyclopropylcarbaldehyde 5 in nitroaldol, cyanohydrin, Mukaiyama aldol, and Sakurai reactions, contrasting the low diastereoselectivities generally observed in additions to cyclopropylcarbaldehydes.

Item Type:Article
Institutions: Chemistry and Pharmacy > Institut für Organische Chemie > Lehrstuhl Prof. Dr. Oliver Reiser
Identification Number:
ValueType
10.1016/S0040-4039(97)01065-4DOI
Subjects:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Unknown
Owner:Helge Knüttel (ADMIN)
Deposited On:23 Aug 2006
Last Modified:05 Aug 2009 15:22
Item ID:292
Owner Only: item control page