Kreuder, Reinhard and Rein, Tobias and Reiser, Oliver (1997) Versatile Stereocontrol in Kinetic Resolution of a Diphenylphosphinyl-Protected α-Amino Aldehyde by Reaction with Chiral Phosphonates. Tetrahedron Letters 38 (52), pp. 9035-9038.
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In kinetic resolutions of the racemic aldehyde 1 by reaction with chiral phosphonates of type 2, all of which contain the same chiral auxiliary in the same enantiomeric form, any of the four diastereomers 3a, 3b, 4a or 4b can be obtained as the main product by an appropriate choice of reaction parameters (geometric selectivities from 66:34 to 98:2, diastereomer ratios between 93:7 and ≥99:1). The ...
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|Date:||29 December 1997|
|Institutions:||Chemistry and Pharmacy > Institut für Organische Chemie > Lehrstuhl Prof. Dr. Oliver Reiser|
|Subjects:||500 Science > 540 Chemistry & allied sciences|
|Refereed:||Yes, this version has been refereed|
|Created at the University of Regensburg:||Unknown|
|Owner:||Helge Knüttel (ADMIN)|
|Deposited On:||23 Aug 2006|
|Last Modified:||05 Aug 2009 13:22|