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Versatile Stereocontrol in Kinetic Resolution of a Diphenylphosphinyl-Protected α-Amino Aldehyde by Reaction with Chiral Phosphonates

Kreuder, Reinhard and Rein, Tobias and Reiser, Oliver (1997) Versatile Stereocontrol in Kinetic Resolution of a Diphenylphosphinyl-Protected α-Amino Aldehyde by Reaction with Chiral Phosphonates. Tetrahedron Letters 38 (52), pp. 9035-9038.

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Other URL: http://dx.doi.org/10.1016/S0040-4039(97)10428-2


Abstract

In kinetic resolutions of the racemic aldehyde 1 by reaction with chiral phosphonates of type 2, all of which contain the same chiral auxiliary in the same enantiomeric form, any of the four diastereomers 3a, 3b, 4a or 4b can be obtained as the main product by an appropriate choice of reaction parameters (geometric selectivities from 66:34 to 98:2, diastereomer ratios between 93:7 and ≥99:1). The ...

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Item Type:Article
Date:29 December 1997
Institutions:Chemistry and Pharmacy > Institut für Organische Chemie > Lehrstuhl Prof. Dr. Oliver Reiser
Identification Number:
ValueType
10.1016/S0040-4039(97)10428-2DOI
Subjects:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Unknown
Owner: Helge Knüttel (ADMIN)
Deposited On:23 Aug 2006
Last Modified:05 Aug 2009 13:22
Item ID:293
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