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Parallel Kinetic Resolution of Racemic Aldehydes by Use of Asymmetric Horner-Wadsworth-Emmons Reactions

Pedersen, Torben M. and Jensen, Jakob F. and Humble, Rikke E. and Rein, Tobias and Tanner, David and Bodmann, Kerstin and Reiser, Oliver (2000) Parallel Kinetic Resolution of Racemic Aldehydes by Use of Asymmetric Horner-Wadsworth-Emmons Reactions. Organic Letters 2 (4), pp. 535-538.

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Other URL: http://dx.doi.org/10.1021/ol991387h


Abstract

A racemic aldehyde can undergo parallel kinetic resolution (PKR) by simultaneous reaction with two different chiral phosphonates, differing either in the structure of the chiral auxiliary or in the structure of the phosphoryl group (i.e., one (E)- and one (Z)-selective reagent). This strategy allows conversion of a racemic aldehyde to two different, synthetically useful chiral products with ...

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Item Type:Article
Date:24 February 2000
Institutions:Chemistry and Pharmacy > Institut für Organische Chemie > Lehrstuhl Prof. Dr. Oliver Reiser
Identification Number:
ValueType
10.1021/ol991387hDOI
Subjects:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Unknown
Owner: Helge Knüttel (ADMIN)
Deposited On:29 Aug 2006
Last Modified:05 Aug 2009 13:22
Item ID:307
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