Deutsch
Böhm, Claudius and Schinnerl, Marina and Bubert, Christian and Zabel, Manfred and Labahn, Thomas and Parisini, Emilio and Reiser, Oliver (2000) A New Strategy for the Stereoselective Synthesis of 1,2,3-trisubstituted Cyclopropanes. Eur. J. Org. Chem. 2000 (16), pp. 2955-2965.
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Other URL: http://dx.doi.org/10.1002/1099-0690(200008)2000:16<2955::AID-EJOC2955>3.0.CO;2-3
Abstract
The stereoselective synthesis of highly functionalized 1,2,3-trisubstituted cyclopropanes 1 and 2, starting from readily available furans 3 or N-protected pyrrole 4, is described. Furthermore, exceptionally high diastereocontrol in agreement with the Felkin-Anh model was observed for the addition of nucleophiles to the title compounds.
| Item Type: | Article | ||||
|---|---|---|---|---|---|
| Institutions: | Chemistry and Pharmacy > Institut für Organische Chemie > Lehrstuhl Prof. Dr. Oliver Reiser | ||||
| Identification Number: |
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| Keywords: | Aldol reactions; Amino aldehydes; Donor-acceptor cyclopropanes; Felkin-Anh rule; Nucleophilic additions | ||||
| Subjects: | 500 Science > 540 Chemistry & allied sciences | ||||
| Status: | Published | ||||
| Refereed: | Yes, this version has been refereed | ||||
| Created at the University of Regensburg: | Unknown | ||||
| Owner: | Helge Knüttel (ADMIN) | ||||
| Deposited On: | 29 Aug 2006 | ||||
| Last Modified: | 05 Aug 2009 15:22 | ||||
| Item ID: | 314 |
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