Böhm, Claudius and Schinnerl, Marina and Bubert, Christian and Zabel, Manfred and Labahn, Thomas and Parisini, Emilio and Reiser, Oliver (2000) A New Strategy for the Stereoselective Synthesis of 1,2,3-trisubstituted Cyclopropanes. Eur. J. Org. Chem. 2000 (16), pp. 2955-2965.
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The stereoselective synthesis of highly functionalized 1,2,3-trisubstituted cyclopropanes 1 and 2, starting from readily available furans 3 or N-protected pyrrole 4, is described. Furthermore, exceptionally high diastereocontrol in agreement with the Felkin-Anh model was observed for the addition of nucleophiles to the title compounds.
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|Institutions:||Chemistry and Pharmacy > Institut für Organische Chemie > Lehrstuhl Prof. Dr. Oliver Reiser|
|Keywords:||Aldol reactions; Amino aldehydes; Donor-acceptor cyclopropanes; Felkin-Anh rule; Nucleophilic additions|
|Dewey Decimal Classification:||500 Science > 540 Chemistry & allied sciences|
|Refereed:||Yes, this version has been refereed|
|Created at the University of Regensburg:||Unknown|
|Deposited On:||29 Aug 2006|
|Last Modified:||05 Aug 2009 13:22|