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The Synthesis of Diastereo- and Enantiomerically Pure β-Aminocyclopropane Carboxylic Acids.

Beumer, Raphael and Bubert, Christian and Cabrele, Chiara and Vielhauer, Oliver and Pietzsch, Markus and Reiser, Oliver (2000) The Synthesis of Diastereo- and Enantiomerically Pure β-Aminocyclopropane Carboxylic Acids. Journal of Organic Chemistry 65 (26), pp. 8960-8969.

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Other URL: http://dx.doi.org/10.102/jo005541l


Abstract

The synthesis of diastereo- and enantiomerically pure -aminocyclopropanecarboxylic acids (-ACCs) is described. Starting from pyrrole, (rac)-4 is readily obtained, which was kinetically resolved by enzymatic hydrolysis. Subsequent oxidation of (-)-4 and deformylation gives rise to the cis--ACC derivative (ent)-9, while (+)-10 was converted to the trans--ACC derivative 8. Both 8 and (ent)-9 and ...

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Item Type:Article
Date:29 December 2000
Institutions:Chemistry and Pharmacy > Institut für Organische Chemie > Arbeitskreis Dr. Chiara Cabrele
Chemistry and Pharmacy > Institut für Organische Chemie > Lehrstuhl Prof. Dr. Oliver Reiser
Identification Number:
ValueType
10.102/jo005541lDOI
Subjects:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Unknown
Owner: Helge Knüttel (ADMIN)
Deposited On:01 Sep 2006
Last Modified:05 Aug 2009 13:22
Item ID:315
Owner Only: item control page
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