Schinnerl, Marina and Seitz, Michael and Kaiser, Anja and Reiser, Oliver (2001) Applications of Bis(oxazoline) Ligands in Catalysis: Asymmetric 1,2- and 1,4-Addition of ZnR₂ to Carbonyl Compounds. Organic Letters 3 (26), pp. 4259-4262.
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Other URL: http://dx.doi.org/10.1021/ol016925g
The enantioselective addition of ZnR2 to aldehydes (1,2) and cyclic enones (1,4) was accomplished using bis(oxazolines) as chiral ligands. The requirement for hydroxymethylene side chains in the ligands strongly suggests that bimetallic catalysts are decisive for high enantiocontrol in these additions.
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|Date:||27 December 2001|
|Institutions:||Chemistry and Pharmacy > Institut für Organische Chemie > Lehrstuhl Prof. Dr. Oliver Reiser|
|Subjects:||500 Science > 540 Chemistry & allied sciences|
|Refereed:||Yes, this version has been refereed|
|Created at the University of Regensburg:||Unknown|
|Deposited On:||01 Sep 2006|
|Last Modified:||05 Aug 2009 13:22|