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Applications of Bis(oxazoline) Ligands in Catalysis: Asymmetric 1,2- and 1,4-Addition of ZnR₂ to Carbonyl Compounds

Schinnerl, Marina and Seitz, Michael and Kaiser, Anja and Reiser, Oliver (2001) Applications of Bis(oxazoline) Ligands in Catalysis: Asymmetric 1,2- and 1,4-Addition of ZnR₂ to Carbonyl Compounds. Organic Letters 3 (26), pp. 4259-4262.

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Other URL: http://dx.doi.org/10.1021/ol016925g


Abstract

The enantioselective addition of ZnR2 to aldehydes (1,2) and cyclic enones (1,4) was accomplished using bis(oxazolines) as chiral ligands. The requirement for hydroxymethylene side chains in the ligands strongly suggests that bimetallic catalysts are decisive for high enantiocontrol in these ...

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Item Type:Article
Date:27 December 2001
Institutions:Chemistry and Pharmacy > Institut für Organische Chemie > Lehrstuhl Prof. Dr. Oliver Reiser
Identification Number:
ValueType
10.1021/ol016925gDOI
Subjects:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Unknown
Owner: Helge Knüttel (ADMIN)
Deposited On:01 Sep 2006
Last Modified:05 Aug 2009 13:22
Item ID:325
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