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Immobilisation of bis(oxazoline)-copper complexes on clays and nanocomposites. Influence of different parameters on activity and selectivity

Fraile, Jose M. and Garcia, Jose I. and Harmer, Mark A. and Herrerias, Clara I. and Mayoral, Jose A. and Reiser, Oliver and Werner, Heiko (2002) Immobilisation of bis(oxazoline)-copper complexes on clays and nanocomposites. Influence of different parameters on activity and selectivity. Journal of Materials Chemistry 12, pp. 3290-3295.

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Other URL: http://www.rsc.org/Publishing/Journals/JM/article.asp?doi=b203849h


Abstract

Bis(oxazoline)–copper complexes, immobilised by electrostatic interactions on Laponite and Nafion/silica nanocomposites, have been tested as catalysts in the cyclopropanation of styrene with ethyl diazoacetate. Several factors play a decisive role in the outcome of the reaction. Firstly, the nature of the solid counterion is important, with perfluorosulfonic solids being the best in this regard. ...

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Item Type:Article
Date:2002
Institutions:Chemistry and Pharmacy > Institut für Organische Chemie > Lehrstuhl Prof. Dr. Oliver Reiser
Identification Number:
ValueType
10.1039/b203849hDOI
Subjects:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Unknown
Owner: Helge Knüttel (ADMIN)
Deposited On:04 Sep 2006
Last Modified:05 Aug 2009 13:22
Item ID:329
Owner Only: item control page
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