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Facile Asymmetric Synthesis of the Core Nuclei of Xanthanolides, Guaianolides and Eudesmanolides

Nosse, Bernd and Chhor, Rakeshwar B. and Jeong, Won Boo and Böhm, Claudius and Reiser, Oliver (2003) Facile Asymmetric Synthesis of the Core Nuclei of Xanthanolides, Guaianolides and Eudesmanolides. Organic Letters 5 (6), pp. 941-944.

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Other URL: http://dx.doi.org/10.1021/ol034141s


Abstract

Bicyclic and tricyclic -butyrolactones with 5,7-, 5,6,5-, 5,6,6-, or 5,7,5-fused ring systems, being found in xanthanolides, eudesmanolides, and guaianolides, were readily synthesized from methyl furan-2-carboxylic acid. Key steps were a copper(I)-catalyzed asymmetric cyclopropanation, Sakurai allylations, intramolecular ene reactions, and ring-closing metathesis ...

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Item Type:Article
Date:20 March 2003
Institutions:Chemistry and Pharmacy > Institut für Organische Chemie > Lehrstuhl Prof. Dr. Oliver Reiser
Identification Number:
ValueType
10.1021/ol034141sDOI
Subjects:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Unknown
Owner: Helge Knüttel (ADMIN)
Deposited On:04 Sep 2006
Last Modified:05 Aug 2009 13:22
Item ID:340
Owner Only: item control page
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