Seitz, Michael and Kaiser, Anja and Powell, Douglas R. and Borovik, Andrew S. and Reiser, Oliver (2004) Predetermined helical chirality in octahedral complexes with a novel pentadentate C₂-symmetric chiral bis(oxazoline) ligand. Advanced Synthesis & Catalysis 346 (7), pp. 737-741.
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Other URL: http://dx.doi.org/10.1002/adsc.200404020
The first example of the pentadentate bis(oxazolines) has been synthesized using a modular approach that readily provides access to this ligand class. This ligand allows the controlled transfer of carbon-centered to octahedral, metal-centered chirality, as demonstrated both in the solid state as well as in solution. The characteristic CD band has been identified for dicationic, octahedral transition metal complexes with the Δ2-configuration.
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|Institutions:||Chemistry and Pharmacy > Institut für Organische Chemie > Lehrstuhl Prof. Dr. Oliver Reiser|
|Keywords:||chirality; circular dichroism; helical structures; structure elucidation; transition metals|
|Subjects:||500 Science > 540 Chemistry & allied sciences|
|Refereed:||Yes, this version has been refereed|
|Created at the University of Regensburg:||Unknown|
|Deposited On:||04 Sep 2006|
|Last Modified:||05 Aug 2009 13:22|