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Predetermined helical chirality in octahedral complexes with a novel pentadentate C₂-symmetric chiral bis(oxazoline) ligand

Seitz, Michael and Kaiser, Anja and Powell, Douglas R. and Borovik, Andrew S. and Reiser, Oliver (2004) Predetermined helical chirality in octahedral complexes with a novel pentadentate C₂-symmetric chiral bis(oxazoline) ligand. Advanced Synthesis & Catalysis 346 (7), pp. 737-741.

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Other URL: http://dx.doi.org/10.1002/adsc.200404020


Abstract

The first example of the pentadentate bis(oxazolines) has been synthesized using a modular approach that readily provides access to this ligand class. This ligand allows the controlled transfer of carbon-centered to octahedral, metal-centered chirality, as demonstrated both in the solid state as well as in solution. The characteristic CD band has been identified for dicationic, octahedral transition metal complexes with the Δ2-configuration.


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Item Type:Article
Date:2004
Institutions:Chemistry and Pharmacy > Institut für Organische Chemie > Lehrstuhl Prof. Dr. Oliver Reiser
Identification Number:
ValueType
10.1002/adsc.200404020DOI
Keywords:chirality; circular dichroism; helical structures; structure elucidation; transition metals
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Unknown
Deposited On:04 Sep 2006
Last Modified:05 Aug 2009 13:22
Item ID:344
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