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Helical, non-racemic inorganic-organic hybrid polymers of cadmium halides with pentadentate bis(oxazoline) ligands

Seitz, Michael and Kaiser, Anja and Stempfhuber, Sabine and Zabel, Manfred and Reiser, Oliver (2004) Helical, non-racemic inorganic-organic hybrid polymers of cadmium halides with pentadentate bis(oxazoline) ligands. Journal of the American Chemical Society 126 (37), pp. 11426-11427.

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Other URL: http://dx.doi.org/10.1021/ja0469784


Abstract

A chiral, nonracemic pentadentate pyridine bis(oxazoline) ligand forms unprecedented P-helical inorganic-organic hybrid polymers with cadmium halides. The one-dimensional chains consist of 2-configured pentagonal-bipyramidal cadmium complexes with metal-centered chirality bridged by [CdX4]2- tetrahedra via shared halide atoms. In the solid state, the overall helicity exhibits strongly directed ...

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Item Type:Article
Date:22 September 2004
Institutions:Chemistry and Pharmacy > Institut für Organische Chemie > Lehrstuhl Prof. Dr. Oliver Reiser
Identification Number:
ValueType
10.1021/ja0469784DOI
Subjects:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Unknown
Owner: Helge Knüttel (ADMIN)
Deposited On:05 Sep 2006
Last Modified:05 Aug 2009 13:22
Item ID:350
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